Voltammetric determination of facilitated ion transfer across the water/1,2-dichloroethane interface
Küçük Resim Yok
Tarih
2014
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
PLEIADES PUBLISHING INC
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The facilitated transfer characteristics of Cd2+ ion by 4-morpholinoacetophenone-4-ethyl-3-thiosemicarbazone (MAPET) across water/1,2-dicholoroethane (1,2-DCE) interface and its electrochemical properties were investigated by voltammetric measurements. Cyclic voltammetry (CV) was employed to examine the transfer in the conditions of the ligand (organic phase) in excess and the obtained transfer peaks have reversible nature at different metal concentrations and scan rates. The dependence of the obtained half-wave transfer potential on MAPET concentration showed that the equilibrium is effectively displaced towards a 1: 3 (Cd2+: ligand) stoichiometry with an association constant of log beta (3) (0) = 12.96 +/- 0.09 for the Cd2+ ion, corresponding to the TIC/TID mechanism.
Açıklama
Anahtar Kelimeler
Cd2+ ion, thiosemicarbazone, cyclic voltammetry, facilitated ion transfer, ITIES
Kaynak
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
WoS Q Değeri
Q4
Scopus Q Değeri
Q3
Cilt
50
Sayı
2
