Voltammetric determination of facilitated ion transfer across the water/1,2-dichloroethane interface

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dc.contributor.authorBaslak, Canan
dc.contributor.authorAtalay, Tevfik
dc.date.accessioned2020-03-26T18:58:46Z
dc.date.available2020-03-26T18:58:46Z
dc.date.issued2014
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe facilitated transfer characteristics of Cd2+ ion by 4-morpholinoacetophenone-4-ethyl-3-thiosemicarbazone (MAPET) across water/1,2-dicholoroethane (1,2-DCE) interface and its electrochemical properties were investigated by voltammetric measurements. Cyclic voltammetry (CV) was employed to examine the transfer in the conditions of the ligand (organic phase) in excess and the obtained transfer peaks have reversible nature at different metal concentrations and scan rates. The dependence of the obtained half-wave transfer potential on MAPET concentration showed that the equilibrium is effectively displaced towards a 1: 3 (Cd2+: ligand) stoichiometry with an association constant of log beta (3) (0) = 12.96 +/- 0.09 for the Cd2+ ion, corresponding to the TIC/TID mechanism.en_US
dc.description.sponsorshipSelcuk UniversitySelcuk University [BAP-07201027]en_US
dc.description.sponsorshipThe authors are indebted to the Scientific Research Projects (BAP-07201027) of Selcuk University for financial support.en_US
dc.identifier.doi10.1134/S1023193513080041en_US
dc.identifier.endpage185en_US
dc.identifier.issn1023-1935en_US
dc.identifier.issn1608-3342en_US
dc.identifier.issue2en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage180en_US
dc.identifier.urihttps://dx.doi.org/10.1134/S1023193513080041
dc.identifier.urihttps://hdl.handle.net/20.500.12395/31280
dc.identifier.volume50en_US
dc.identifier.wosWOS:000331960700012en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPLEIADES PUBLISHING INCen_US
dc.relation.ispartofRUSSIAN JOURNAL OF ELECTROCHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCd2+ ionen_US
dc.subjectthiosemicarbazoneen_US
dc.subjectcyclic voltammetryen_US
dc.subjectfacilitated ion transferen_US
dc.subjectITIESen_US
dc.titleVoltammetric determination of facilitated ion transfer across the water/1,2-dichloroethane interfaceen_US
dc.typeArticleen_US

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