Molecularly Functionalized Silicon Substrates for Orientation Control of the Microphase Separation of PS-b-PMMA and PS-b-PDMS Block Copolymer Systems

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dc.contributor.authorBorah, Dipu
dc.contributor.authorOzmen, Mustafa
dc.contributor.authorRasappa, Sozaraj
dc.contributor.authorShaw, Matthew T.
dc.contributor.authorHolmes, Justin D.
dc.contributor.authorMorris, Michael A.
dc.date.accessioned2020-03-26T18:42:32Z
dc.date.available2020-03-26T18:42:32Z
dc.date.issued2013
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe use of block copolymer (BCP) thin films to generate nanostructured surfaces for device and other applications requires precise control of interfacial energies to achieve the desired domain orientation. Usually, the surface chemistry is engineered through the use of homo- or random copolymer brushes grown or attached to the surface. Herein, we demonstrate a facile, rapid, and tunable approach to surface functionalization using a molecular approach based on ethylene glycol attachment to the surface. The effectiveness of the molecular approach is demonstrated for the microphase separation of PS-b-PMMA and PS-b-PDMS BCPs in thin films and the development of nanoscale features at the substrate.en_US
dc.description.sponsorshipEUEuropean Union (EU) [245565]; Science Foundation IrelandScience Foundation Ireland [09/IN.1/602]en_US
dc.description.sponsorshipFinancial support for this work is provided by the EU FP7 NMP project, LAMAND (Grant Number 245565) project, and the Science Foundation Ireland (Grant Number 09/IN.1/602) and is gratefully acknowledged.en_US
dc.identifier.doi10.1021/la304140qen_US
dc.identifier.endpage2820en_US
dc.identifier.issn0743-7463en_US
dc.identifier.issue9en_US
dc.identifier.pmid23363319en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage2809en_US
dc.identifier.urihttps://dx.doi.org/10.1021/la304140q
dc.identifier.urihttps://hdl.handle.net/20.500.12395/29654
dc.identifier.volume29en_US
dc.identifier.wosWOS:000315844100003en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherAMER CHEMICAL SOCen_US
dc.relation.ispartofLANGMUIRen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleMolecularly Functionalized Silicon Substrates for Orientation Control of the Microphase Separation of PS-b-PMMA and PS-b-PDMS Block Copolymer Systemsen_US
dc.typeArticleen_US

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