Initiated Chemical Vapor Deposition of Ph Responsive Poly(2-diisopropylamino)ethyl Methacrylate Thin Films
Yükleniyor...
Dosyalar
Tarih
2012
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Sa
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Poly(2-(diisopropylamino)ethyl methacrylate) (PDPAEMA) thin films were deposited on low temperature substrates by initiated chemical vapor deposition (iCVD) method using tertbutyl peroxide as an initiator. Very high deposition rates up to 38 nm/min were observed at low filament temperatures due to the use of the initiator. Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy show the formation of PDPAEMA films with high retention of tertiary amine functionality which is responsible for pH induced changes in the wetting behavior of the surfaces. As-deposited PDPAEMA thin films on flat Si surface showed a reversible switching of water contact angle values between 87 degrees and 28 degrees; after successive treatments of high and low pH water solutions, respectively. Conformal and non-damaging nature of iCVD allowed to functionalize fragile and rough electrospun poly(methyl methacrylate) fiber mat surfaces by PDPAEMA, which creates a surface with a switching behavior between superhydrophobic and approaching superhydrophilic with contact angle values of 155 +/- 3 degrees and 22 +/- 5 degrees, respectively. (C) 2012 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
Chemical vapor deposition, Stimuli responsive polymers, Contact angle, Tunable wettability, Functional polymer coatings
Kaynak
Thin Solid Films
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
520
Sayı
21
Künye
Karaman, M., Cabuk, N., (2012). Initiated Chemical Vapor Deposition of Ph Responsive Poly(2-diisopropylamino)ethyl Methacrylate Thin Films. Thin Solid Films, 520(21), 6484-6488.
DOI:10.1016/j.tsf.2012.06.083
