Initiated Chemical Vapor Deposition of Ph Responsive Poly(2-diisopropylamino)ethyl Methacrylate Thin Films

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dc.contributor.authorKaraman, M.
dc.contributor.authorCabuk, N.
dc.date.accessioned2020-03-26T18:30:43Z
dc.date.available2020-03-26T18:30:43Z
dc.date.issued2012
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractPoly(2-(diisopropylamino)ethyl methacrylate) (PDPAEMA) thin films were deposited on low temperature substrates by initiated chemical vapor deposition (iCVD) method using tertbutyl peroxide as an initiator. Very high deposition rates up to 38 nm/min were observed at low filament temperatures due to the use of the initiator. Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy show the formation of PDPAEMA films with high retention of tertiary amine functionality which is responsible for pH induced changes in the wetting behavior of the surfaces. As-deposited PDPAEMA thin films on flat Si surface showed a reversible switching of water contact angle values between 87 degrees and 28 degrees; after successive treatments of high and low pH water solutions, respectively. Conformal and non-damaging nature of iCVD allowed to functionalize fragile and rough electrospun poly(methyl methacrylate) fiber mat surfaces by PDPAEMA, which creates a surface with a switching behavior between superhydrophobic and approaching superhydrophilic with contact angle values of 155 +/- 3 degrees and 22 +/- 5 degrees, respectively. (C) 2012 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [110M088]en_US
dc.description.sponsorshipThis research was supported by the Scientific and Technological Research Council of Turkey (TUBITAK) (project no. 110M088). We would like to thank Dr. Ozcan Koysuren at Selcuk University for his help during the electrospinning experiments.en_US
dc.identifier.citationKaraman, M., Cabuk, N., (2012). Initiated Chemical Vapor Deposition of Ph Responsive Poly(2-diisopropylamino)ethyl Methacrylate Thin Films. Thin Solid Films, 520(21), 6484-6488. DOI:10.1016/j.tsf.2012.06.083
dc.identifier.doi10.1016/j.tsf.2012.06.083en_US
dc.identifier.endpage6488en_US
dc.identifier.issn0040-6090en_US
dc.identifier.issue21en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage6484en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.tsf.2012.06.083
dc.identifier.urihttps://hdl.handle.net/20.500.12395/28146
dc.identifier.volume520en_US
dc.identifier.wosWOS:000307286100007en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorKaraman, M.
dc.institutionauthorCabuk, N.
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofThin Solid Filmsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectChemical vapor depositionen_US
dc.subjectStimuli responsive polymersen_US
dc.subjectContact angleen_US
dc.subjectTunable wettabilityen_US
dc.subjectFunctional polymer coatingsen_US
dc.titleInitiated Chemical Vapor Deposition of Ph Responsive Poly(2-diisopropylamino)ethyl Methacrylate Thin Filmsen_US
dc.typeArticleen_US

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