Functional group efects of new calixarene derivatives on catalytic and enantioselective behavior of lipase

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dc.contributor.authorDogan, Vildan.
dc.contributor.authorSayin, Serkan.
dc.contributor.authorUyanik, Arzu.
dc.contributor.authorYilmaz, Mustafa.
dc.date.accessioned2020-03-26T20:14:22Z
dc.date.available2020-03-26T20:14:22Z
dc.date.issued2019
dc.departmentSelçuk Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractIn this study, two new calixarene derivatives bearing thiourea and carbamate moieties were synthesized and characterized. Moreover, thiourea- and carbamate-bridged calixarene derivatives with Fe3O4 magnetic nanoparticle were employed for the first time as the convenient additives in the encapsulation process of lipase. The results of catalytic activity and enantioselectivity of the encapsulated lipases in the hydrolysis reaction of racemic flurbiprofen methyl ester indicate that both of the encapsulated lipases (Enc-TuC[4]@Fe3O4 and Enc-CbC[4]@Fe3O4) exhibit higher conversion and enantioselectivity compared to the free-encapsulated lipase (Enc-Lipase). However, the highest affinities result was obtained when the encapsulated lipase (Enc-CbC[4]@Fe3O4) was used in the kinetic resolution reaction of racemic flurbiprofen methyl ester.en_US
dc.description.sponsorshipResearch Foundation of Selcuk University (BAP), Konya, Turkey [15201004]en_US
dc.description.sponsorshipThis work was supported by the Research Foundation of Selcuk University (BAP grant no. 15201004), Konya, Turkey.en_US
dc.identifier.citationDogan, V., Sayin, S., Uyanik, A., Yilmaz, M. (2019). Functional Group Effects of New Calixarene Derivatives on Catalytic and Enantioselective Behavior of Lipase. Polycyclic Aromatic Compounds, 39(4), 318-331.
dc.identifier.doi10.1080/10406638.2017.1326949en_US
dc.identifier.endpage331en_US
dc.identifier.issn1040-6638en_US
dc.identifier.issn1563-5333en_US
dc.identifier.issue4en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage318en_US
dc.identifier.urihttps://dx.doi.org/10.1080/10406638.2017.1326949
dc.identifier.urihttps://hdl.handle.net/20.500.12395/37867
dc.identifier.volume39en_US
dc.identifier.wosWOS:000481437500003en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorDogan, Vildan.
dc.institutionauthorUyanik, Arzu.
dc.institutionauthorYilmaz, Mustafa.
dc.language.isoenen_US
dc.publisherTAYLOR & FRANCIS LTDen_US
dc.relation.ispartofPOLYCYCLIC AROMATIC COMPOUNDSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCalixareneen_US
dc.subjectenantioselectivityen_US
dc.subjectFe(3)O(4)nanoparticlesen_US
dc.subjectflurbiprofenen_US
dc.subjectlipaseen_US
dc.titleFunctional group efects of new calixarene derivatives on catalytic and enantioselective behavior of lipaseen_US
dc.typeArticleen_US

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