Synthesis and structural and electrochemical characterization of novel macrocyclic vic-dioxime ligand and its mononuclear transition and nontransition metal complexes

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dc.contributor.authorDeveci, Pervin
dc.contributor.authorTaner, Bilge
dc.contributor.authorKilic, Zeynel
dc.contributor.authorSolak, Ali Osman
dc.contributor.authorOzcan, Emine
dc.date.accessioned2020-03-26T18:31:29Z
dc.date.available2020-03-26T18:31:29Z
dc.date.issued2012
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe reaction of N-(4-aminophenyl)aza-15-crown-5 (1) with anti-chlorophenylglyoxime (2) produces a novel azacrown ether containing vic-dioxime, N-(4-aminophenyl)aza-15-crown-5-phenylglyoxime (LH2). LH2 reacts with Ni(II), Cu(II), Co(II), Cd(II), and Zn(II) ions to yield the mononuclear transition and nontransition metal complexes [M(LH)(2)] (M = Ni and Cu), [M(LH)(2) (H2O)(2)] (M = Co), and [M(LH)(H2O) (Cl)] (M = Cd and Zn). The structural features of LH2 were studied using several techniques including elemental analysis. Fourier transform infrared spectroscopy (FT-IR,), ultraviolet visible (UV-Vis), mass spectrometry (MS), 1-dimensional (1D) H-1-NMR and (CNMR)-C-13, distortionless enhancement by polarization transfer (DEPT) 2-dimensional (2D) heteronuclear single-quantum coherence (HSQC), and heteronuclear multiple-bond correlation (HMBC) techniques. The structures of the complexes were confirmed by elemental analyses and with the use of magnetic susceptibility measurements, MS, UV-Vis, FT-IR, H-1-NMR and C-13-NMR techniques. The redox behaviors of the ligand and its Complexes were verified with cyclic voltammetry (CV) at a. glassy carbon (GC) electrode in 0.1 M tetrabutylammoniumtetrafluoroborate (TBATFB) in dimethyl sulfoxide (DMSO).en_US
dc.description.sponsorshipSelcuk UniversitySelcuk University [08101030]en_US
dc.description.sponsorshipThis work was supported by the Research Fund of Selcuk University Project Number 08101030 under thesis worken_US
dc.identifier.doi10.3906/kim-1106-50en_US
dc.identifier.endpage36en_US
dc.identifier.issn1300-0527en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage25en_US
dc.identifier.urihttps://dx.doi.org/10.3906/kim-1106-50
dc.identifier.urihttps://hdl.handle.net/20.500.12395/28458
dc.identifier.volume36en_US
dc.identifier.wosWOS:000300209600002en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakTR-Dizinen_US
dc.language.isoenen_US
dc.publisherSCIENTIFIC TECHNICAL RESEARCH COUNCIL TURKEY-TUBITAKen_US
dc.relation.ispartofTURKISH JOURNAL OF CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectvic-Dioximeen_US
dc.subjectazacrown etheren_US
dc.subjecttransition metal complexesen_US
dc.subjectmass spectroscopyen_US
dc.subjectcyclic voltammetryen_US
dc.titleSynthesis and structural and electrochemical characterization of novel macrocyclic vic-dioxime ligand and its mononuclear transition and nontransition metal complexesen_US
dc.typeArticleen_US

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