Complexation Properties and Synthesis of a Novel Schiff Base with Triphenylene Nucleus
Yükleniyor...
Dosyalar
Tarih
2010
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
ELSEVIER SCIENCE BV
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
We presented the synthesis of a novel Schiff base and its complexation properties with some transition metal ions in this work. For this, the 2,3,4,6,7,10,11 hexahydroxytriphenylene (HHTP) as starting material was synthesized according to known procedure. Moreover, the 2-((2-chloroethylimino)methyl) phenol material was prepared with reaction of salicylaldehyde and 2-chloroethylamine hydrochloride. To give the 2,3,4,6,7,10,11-hexakis(salicyliminoethoxy)triphenylene (HSE-TP) as a novel Schiff base, the HHTP were treated with 2-((2-chloroethylimino)methyl)phenol in acetone media. Complexation properties of this Schiff base were investigated towards Ni(II), Cu(II),Co(II), Zn(II), Pd(II) and Cd(II) as transition metals. The structures of these new compounds (ligand and complexes) were characterized with FT-IR, magnetic susceptibility measurement, thermal methods (TGA), H-1 NMR and elemental analyses.
Açıklama
Anahtar Kelimeler
Complexation, Triphenylene, Schiff base, Transition metals
Kaynak
Journal of Hazardous Materials
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
183
Sayı
Künye
Koçyiğit, Ö., Kurşunlu, A. N., Güler, E., (2010). Complexation Properties and Synthesis of a Novel Schiff Base with Triphenylene Nucleus. Journal of Hazardous Materials, 183, 334-340. doi:10.1016/j.jhazmat.2010.07.029
