Complexation Properties and Synthesis of a Novel Schiff Base with Triphenylene Nucleus

Yükleniyor...
Küçük Resim

Tarih

2010

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

ELSEVIER SCIENCE BV

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

We presented the synthesis of a novel Schiff base and its complexation properties with some transition metal ions in this work. For this, the 2,3,4,6,7,10,11 hexahydroxytriphenylene (HHTP) as starting material was synthesized according to known procedure. Moreover, the 2-((2-chloroethylimino)methyl) phenol material was prepared with reaction of salicylaldehyde and 2-chloroethylamine hydrochloride. To give the 2,3,4,6,7,10,11-hexakis(salicyliminoethoxy)triphenylene (HSE-TP) as a novel Schiff base, the HHTP were treated with 2-((2-chloroethylimino)methyl)phenol in acetone media. Complexation properties of this Schiff base were investigated towards Ni(II), Cu(II),Co(II), Zn(II), Pd(II) and Cd(II) as transition metals. The structures of these new compounds (ligand and complexes) were characterized with FT-IR, magnetic susceptibility measurement, thermal methods (TGA), H-1 NMR and elemental analyses.

Açıklama

Anahtar Kelimeler

Complexation, Triphenylene, Schiff base, Transition metals

Kaynak

Journal of Hazardous Materials

WoS Q Değeri

Q1

Scopus Q Değeri

Q1

Cilt

183

Sayı

Künye

Koçyiğit, Ö., Kurşunlu, A. N., Güler, E., (2010). Complexation Properties and Synthesis of a Novel Schiff Base with Triphenylene Nucleus. Journal of Hazardous Materials, 183, 334-340. doi:10.1016/j.jhazmat.2010.07.029