Synthesis and Characterization of Tripodal Oxy-Schiff base (2,4,6-Tris(4-Carboxymethylenephenylimino-4 '-formylphenoxy)-1,3,5-triazine) and the Thermal and Magnetic Properties of its Fe(III)/Cr(III) Complexes
Küçük Resim Yok
Tarih
2011
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
SPRINGER
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Eight new trinuclear Fe(III)/Cr(III) complexes involving tetradentate (N2O2) and pentadentate (N3O2) Schiff bases of (salenH(2)), (salophenH(2)), (saldetaH(2)) and (salpyrH(2)) with 2,4,6-tris(4-carboxymethylenephenylimino-4'-formylphenoxy)-1,3,5-triazine were synthesized. The structure of ligand and complexes were identified using elemental and thermal analysis, magnetic susceptibility, and LC-MS, ICP-AES, H-1 NMR and FT-IR spectral data. All complexes are tripodal-trinuclear. The complexes are low-spin (S = 1/2) distorted octahedral salen- or salophen-capped Fe(III), high-spin (S = 5/2) distorted octahedral saldeta- or salpyr-capped Fe(III) and distorted octahedral (S = 3/2) salen-, salophen-, saldeta- or salpyr-capped Cr(III).
Açıklama
Anahtar Kelimeler
Salen, Salophen, Saldeta, Salpyr, Schiff base, s-Triazine, Fe(III), N2O2, N3O2
Kaynak
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
21
Sayı
3
