Synthesis and Characterization of Tripodal Oxy-Schiff base (2,4,6-Tris(4-Carboxymethylenephenylimino-4 '-formylphenoxy)-1,3,5-triazine) and the Thermal and Magnetic Properties of its Fe(III)/Cr(III) Complexes
dc.contributor.author | Koc, Ziya Erdem | |
dc.contributor.author | Uysal, Saban | |
dc.date.accessioned | 2020-03-26T18:16:24Z | |
dc.date.available | 2020-03-26T18:16:24Z | |
dc.date.issued | 2011 | |
dc.department | Selçuk Üniversitesi | en_US |
dc.description.abstract | Eight new trinuclear Fe(III)/Cr(III) complexes involving tetradentate (N2O2) and pentadentate (N3O2) Schiff bases of (salenH(2)), (salophenH(2)), (saldetaH(2)) and (salpyrH(2)) with 2,4,6-tris(4-carboxymethylenephenylimino-4'-formylphenoxy)-1,3,5-triazine were synthesized. The structure of ligand and complexes were identified using elemental and thermal analysis, magnetic susceptibility, and LC-MS, ICP-AES, H-1 NMR and FT-IR spectral data. All complexes are tripodal-trinuclear. The complexes are low-spin (S = 1/2) distorted octahedral salen- or salophen-capped Fe(III), high-spin (S = 5/2) distorted octahedral saldeta- or salpyr-capped Fe(III) and distorted octahedral (S = 3/2) salen-, salophen-, saldeta- or salpyr-capped Cr(III). | en_US |
dc.identifier.doi | 10.1007/s10904-011-9475-9 | en_US |
dc.identifier.endpage | 406 | en_US |
dc.identifier.issn | 1574-1443 | en_US |
dc.identifier.issn | 1574-1451 | en_US |
dc.identifier.issue | 3 | en_US |
dc.identifier.scopusquality | Q2 | en_US |
dc.identifier.startpage | 400 | en_US |
dc.identifier.uri | https://dx.doi.org/10.1007/s10904-011-9475-9 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12395/26863 | |
dc.identifier.volume | 21 | en_US |
dc.identifier.wos | WOS:000294804500002 | en_US |
dc.identifier.wosquality | Q2 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | SPRINGER | en_US |
dc.relation.ispartof | JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.selcuk | 20240510_oaig | en_US |
dc.subject | Salen | en_US |
dc.subject | Salophen | en_US |
dc.subject | Saldeta | en_US |
dc.subject | Salpyr | en_US |
dc.subject | Schiff base | en_US |
dc.subject | s-Triazine | en_US |
dc.subject | Fe(III) | en_US |
dc.subject | N2O2 | en_US |
dc.subject | N3O2 | en_US |
dc.title | Synthesis and Characterization of Tripodal Oxy-Schiff base (2,4,6-Tris(4-Carboxymethylenephenylimino-4 '-formylphenoxy)-1,3,5-triazine) and the Thermal and Magnetic Properties of its Fe(III)/Cr(III) Complexes | en_US |
dc.type | Article | en_US |