Synthesis of 1,3,5-Tris(4-(4-Nitrophenyliminomethyl)Phenoxymethyl)Benzene as a New Schiff Base and Its Complexation Properties with the (Salen and Salophen)-Bridged Fe/Cr(III)
Yükleniyor...
Dosyalar
Tarih
2010
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
SPRINGER
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
In the present study, we discussed to synthesis of a new Schiff base with nitro groups and its complexation properties with Fe/Cr(III) salen/salophen capped complexes. For this, 1,3,5-tris (formylphenoxymethyl)benzene (1, TRIPOD) involving aldehyde groups was converted to the Schiff base derivative (2, TNPIM-TRIPOD) using 4-nitroaniline. The synthesized compound 2 were reacted with four new trinuclear Fe(III) and Cr(III) complexes involving tetradenta Schiff bases N,N-bis(salicylidene)ethylenediamine-(salenH(2)) or bis(salicylidene)-o-phenylenediamine-(salophenH(2)). Characterization of all compounds was made with elemental analysis, infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), nuclear magnetic resonance (H-1-NMR), and magnetic susceptibility measurement. The complexes can also be characterized as low-spin distorted octahedral Fe(III) and Cr(III) bridged by nitro groups.
Açıklama
Anahtar Kelimeler
Synthesis, Trisaldehyde, Schiff base, 4-Nitroaniline
Kaynak
Journal of Inclusion Phenomena and Macrocyclic Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Q3
Cilt
67
Sayı
03.04.2020
Künye
Koçyiğit, Ö., Güler, E., (2010). Synthesis of 1,3,5-Tris(4-(4-Nitrophenyliminomethyl)Phenoxymethyl)Benzene as a New Schiff Base and Its Complexation Properties with the (Salen and Salophen)-Bridged Fe/Cr(III). Journal of Inclusion Phenomena and Macrocyclic Chemistry, 67(2010), 287-293. Doi:10.1007/s10847-009-9708-5
