Synthesis of 1,3,5-Tris(4-(4-Nitrophenyliminomethyl)Phenoxymethyl)Benzene as a New Schiff Base and Its Complexation Properties with the (Salen and Salophen)-Bridged Fe/Cr(III)

Basit Öğe Kaydı
dc.contributor.authorKoçyiğit, Özcan
dc.contributor.authorGüler, Ersin
dc.date.accessioned2020-03-26T18:05:06Z
dc.date.available2020-03-26T18:05:06Z
dc.date.issued2010
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractIn the present study, we discussed to synthesis of a new Schiff base with nitro groups and its complexation properties with Fe/Cr(III) salen/salophen capped complexes. For this, 1,3,5-tris (formylphenoxymethyl)benzene (1, TRIPOD) involving aldehyde groups was converted to the Schiff base derivative (2, TNPIM-TRIPOD) using 4-nitroaniline. The synthesized compound 2 were reacted with four new trinuclear Fe(III) and Cr(III) complexes involving tetradenta Schiff bases N,N-bis(salicylidene)ethylenediamine-(salenH(2)) or bis(salicylidene)-o-phenylenediamine-(salophenH(2)). Characterization of all compounds was made with elemental analysis, infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), nuclear magnetic resonance (H-1-NMR), and magnetic susceptibility measurement. The complexes can also be characterized as low-spin distorted octahedral Fe(III) and Cr(III) bridged by nitro groups.en_US
dc.description.sponsorshipScientific Research Projects Foundation of Selcuk University (SUBAP)Selcuk University [2006-06101042]en_US
dc.description.sponsorshipWe thank the Scientific Research Projects Foundation of Selcuk University (SUBAP Grant Number 2006-06101042) for financial support of this work produced from a part of O. Kocyigit's PhD Thesis.en_US
dc.identifier.citationKoçyiğit, Ö., Güler, E., (2010). Synthesis of 1,3,5-Tris(4-(4-Nitrophenyliminomethyl)Phenoxymethyl)Benzene as a New Schiff Base and Its Complexation Properties with the (Salen and Salophen)-Bridged Fe/Cr(III). Journal of Inclusion Phenomena and Macrocyclic Chemistry, 67(2010), 287-293. Doi:10.1007/s10847-009-9708-5
dc.identifier.doi10.1007/s10847-009-9708-5en_US
dc.identifier.endpage293en_US
dc.identifier.issn1388-3127en_US
dc.identifier.issn1573-1111en_US
dc.identifier.issue03.04.2020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage287en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-009-9708-5
dc.identifier.urihttps://hdl.handle.net/20.500.12395/25303
dc.identifier.volume67en_US
dc.identifier.wosWOS:000277958600006en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorKoçyiğit, Özcan
dc.institutionauthorGüler, Ersin
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJournal of Inclusion Phenomena and Macrocyclic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectSynthesisen_US
dc.subjectTrisaldehydeen_US
dc.subjectSchiff baseen_US
dc.subject4-Nitroanilineen_US
dc.titleSynthesis of 1,3,5-Tris(4-(4-Nitrophenyliminomethyl)Phenoxymethyl)Benzene as a New Schiff Base and Its Complexation Properties with the (Salen and Salophen)-Bridged Fe/Cr(III)en_US
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim
İsim:
5303.pdf
Boyut:
428.32 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Makale Dosyası
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Kimya/Makale Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu