Synthesis and Characterization of Dendrimeric Melamine Cored [Salen/Salophfe(III)] and [sale N/Salophcr(III)] Capped Complexes and Their Magnetic Behaviors

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dc.contributor.authorUysal, Şaban
dc.contributor.authorKoç, Ziya Erdem
dc.date.accessioned2020-03-26T18:05:05Z
dc.date.available2020-03-26T18:05:05Z
dc.date.issued2010
dc.departmentSelçuk Üniversitesien_US
dc.description.abstract2,4,6-Tris(4-hydroxybenzimino)-1,3.5-triazine [1] 2 has been synthesized from the reaction of 1 equiv. melamine (2.4,6-triamino-1,3,5-triazine) and 3 equiv. 4-hydroxybenzaldehyde. Then, 2,4,6-tris(4-(4,6-dichloro-1,3,5-triazine-2-yloxy)benzimino)-1,3,5-triazine 3 has been synthesized from the reaction of 1 equiv. 2 and 3 equiv. cyanuric chloride. And then, two new triazine centered dendrimeric ligands 2,4,6-tris(4-(4,6-bis(4-carboxyphenyloxy)-1,3,5-triazine-2-yloxy)benzimino)-1,3,5-triazine 4 and 2,4,6-tris(4-(4,6-bis(3,5-dicarboxyphenyloxy)-1,3,5-triazine-2-yloxy)benzimino)-1,3,5-triazine 5 have been synthesized from the reaction of 1 equiv. 3 and 6 equiv 4-hydroxybenzoic acid or 5-hydroxyisophtalic acid. Finally, eight new multinuclear Fe(III) and Cr(III) complexes involving tetradenta Schiff bases N,N'-bis(salicylidene)ethylenediamine-(salenH(2)) or bis(salicylidene)-o-phenylene diamine-(salophH(2)) with 4 or 5 have been synthesized and characterized by means of elemental analysis, H-1 NMR, FT-IR spectroscopy, thermal analyses and magnetic susceptibility measurements. The complexes can also be characterized as low-spin distorted octahedral Fe(III) and Cr(III) bridged by carboxylic acids.en_US
dc.identifier.citationUysal, Ş., Koç, Z. E., (2010). Synthesis and Characterization of Dendrimeric Melamine Cored [Salen/Salophfe(III)] and [sale N/Salophcr(III)] Capped Complexes and Their Magnetic Behaviors. Journal of Hazardous Materials, 175(2010), 532-539. Doi:10.1016/j.jhazmat.2009.10.038
dc.identifier.doi10.1016/j.jhazmat.2009.10.038en_US
dc.identifier.endpage539en_US
dc.identifier.issn0304-3894en_US
dc.identifier.issn1873-3336en_US
dc.identifier.issue01.03.2020en_US
dc.identifier.pmid19906486en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage532en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.jhazmat.2009.10.038
dc.identifier.urihttps://hdl.handle.net/20.500.12395/25300
dc.identifier.volume175en_US
dc.identifier.wosWOS:000274490400066en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.institutionauthorUysal, Şaban
dc.institutionauthorKoç, Ziya Erdem
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofJournal of Hazardous Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjects-Triazineen_US
dc.subjectMelamineen_US
dc.subjectCyanuric Chlorideen_US
dc.subjectSalenen_US
dc.subjectSalophen_US
dc.subjectSchiff Basesen_US
dc.titleSynthesis and Characterization of Dendrimeric Melamine Cored [Salen/Salophfe(III)] and [sale N/Salophcr(III)] Capped Complexes and Their Magnetic Behaviorsen_US
dc.typeArticleen_US

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