Synthesis and Metal Ions Sorption Properties of Styrene-Based Polymers

dc.contributor.authorDeveci, Huseyin
dc.contributor.authorAhmetli, Gulnare
dc.contributor.authorErsoz, Mustafa
dc.contributor.authorKurbanli, Refika
dc.date.accessioned2020-03-26T17:40:21Z
dc.date.available2020-03-26T17:40:21Z
dc.date.issued2009
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractAtactic polystyrene (PS) was chemically modified with maleic (MAH), succinic (SAH), and phtalic (PhAH) anhydrides. Styrene was copolymerized with acrylic (AA) and methacrylic acids (MA). Amount of carboxyl groups (%) bound to polymers was determined in the range of 6.9-25.9. Different modified polystyrenes (MPS) and styrene copolymers were used in the experiments to study Cu(II) and Zn(II) ions adsorption probability and their comparison. Sorption capacity of the polymers for the metal ions were investigated in aqueous media containing different amounts of these ions (540 mg/L) and at different pH values (2.0-6.0). Adsorption behavior of heavy metal ions could be modeled using both the Langmuir and Freundlich isotherms. It was found that the adsorption capacity is highest at pH value of 6, whereas it decreases as the pH value decreases at temperature 25 degrees C +/- 1 degrees C for 240 min. The results obtained from the adsorption capacity experiments for Cu(II) and Zn(II) ions were 3.47-5.45 and 5.42-6.85 mg/g, respectively. The affinity order of polymers for both metal ions was observed as follows: SMAC > SAAC > MPS with MAH > MPS with SAH > MPS with PhAH. The maximum adsorption capacities of SMAC were 6.85mg/g for Zn(II) and 5.45 mg/g for Cu(II). (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 112: 1192-1198, 2009en_US
dc.description.sponsorshipSelcuk University Scientific Research FoundationSelcuk University [07101007]en_US
dc.description.sponsorshipContract grant sponsor: Selcuk University Scientific Research Foundation; contract grant number: Project 07101007.en_US
dc.identifier.doi10.1002/app.29511en_US
dc.identifier.endpage1198en_US
dc.identifier.issn0021-8995en_US
dc.identifier.issn1097-4628en_US
dc.identifier.issue3en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1192en_US
dc.identifier.urihttps://dx.doi.org/10.1002/app.29511
dc.identifier.urihttps://hdl.handle.net/20.500.12395/23888
dc.identifier.volume112en_US
dc.identifier.wosWOS:000264247300010en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWILEYen_US
dc.relation.ispartofJOURNAL OF APPLIED POLYMER SCIENCEen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectstyreneen_US
dc.subjectcopolymerizationen_US
dc.subjectmodificationen_US
dc.subjectpolystyreneen_US
dc.subjectadsorptionen_US
dc.titleSynthesis and Metal Ions Sorption Properties of Styrene-Based Polymersen_US
dc.typeArticleen_US

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