Proton-Coupled Oxygen Reduction at Liquid-Liquid Interfaces Catalyzed by Cobalt Porphine

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dc.contributor.authorHatay, Imren
dc.contributor.authorSu, Bin
dc.contributor.authorLi, Fei
dc.contributor.authorMendez, Manuel Alejandro
dc.contributor.authorKhoury, Tony
dc.contributor.authorGros, Claude P.
dc.contributor.authorBarbe, Jean-Michel
dc.date.accessioned2020-03-26T17:39:49Z
dc.date.available2020-03-26T17:39:49Z
dc.date.issued2009
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractCobalt porphine (COP) dissolved in the organic phase of a biphasic system is used to catalyze O-2 reduction by an electron donor, ferrocene (Fc). Using voltammetry at the interface between two immiscible electrolyte solutions (ITIES), it is possible to drive this catalytic reduction at the interface as a function of the applied potential difference, where aqueous protons and organic electron donors combine to reduce O-2. The current signal observed corresponds to a proton-coupled electron transfer (PCET) reaction, as no current and no reaction can be observed in the absence of either the aqueous acid, COP, c, or O-2.en_US
dc.description.sponsorshipEPFL; Swiss National Science FoundationSwiss National Science Foundation (SNSF) [FNRS 200020-116588]; CNRSCentre National de la Recherche Scientifique (CNRS); Grant Agency of the Czech RepublicGrant Agency of the Czech Republic [203/07/1257]; European Cost Action [D36/007/06]; Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK)en_US
dc.description.sponsorshipThis work was supported by EPFL, the Swiss National Science Foundation (FNRS 200020-116588), CNRS, Grant Agency of the Czech Republic (No. 203/07/1257), and European Cost Action D36/007/06 and CNRS. I.H. and M.E. also gratefully acknowledge the Scientific and Technological Research Council of Turkey (TUBITAK) under the 2212-PhD Scholarship Program.en_US
dc.identifier.doi10.1021/ja904569pen_US
dc.identifier.endpage13459en_US
dc.identifier.issn0002-7863en_US
dc.identifier.issn1520-5126en_US
dc.identifier.issue37en_US
dc.identifier.pmid19715275en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage13453en_US
dc.identifier.urihttps://dx.doi.org/10.1021/ja904569p
dc.identifier.urihttps://hdl.handle.net/20.500.12395/23795
dc.identifier.volume131en_US
dc.identifier.wosWOS:000270186500058en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherAMER CHEMICAL SOCen_US
dc.relation.ispartofJOURNAL OF THE AMERICAN CHEMICAL SOCIETYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleProton-Coupled Oxygen Reduction at Liquid-Liquid Interfaces Catalyzed by Cobalt Porphineen_US
dc.typeArticleen_US

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