Fractionation effects of polystyrene on acylation reaction and their adhesive and corrosive properties

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dc.contributor.authorOkudan, A.
dc.contributor.authorSinan, F.
dc.date.accessioned2020-03-26T18:42:00Z
dc.date.available2020-03-26T18:42:00Z
dc.date.issued2013
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractFirst, polystyrene (PS) was fractionated using solvent-precipitation methods; then the chemical modification of PS was investigated in the presence of Lewis acid [BF3 center dot O(C2H5)(2)] catalyst with some anhydrides such as phthalic anhydride, glutaric anhydride, maleic anhydride, and propionic anhydride. The amount of the polyfunctional groups bonded to polymer structures changed depending on the molecular weight of the polymer, and more functional groups connected to the highest-molecular-weight fraction. The amount of the bonded functional groups was determined with the chemical analysis method. The structures of PS functionalized with anhydrides were confirmed by FTIR, H-1 NMR, and thermogravimetric studies. Their adhesion capability and corrosion resistance against metals have been investigated under various conditions. The results showed that the addition of functional groups to PS increases its adhesion capability and corrosion resistance. This increase is attributed to the quantity of the functional groups bonded to PS.en_US
dc.identifier.doi10.1007/s11998-013-9479-1en_US
dc.identifier.endpage640en_US
dc.identifier.issn1547-0091en_US
dc.identifier.issue5en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage631en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s11998-013-9479-1
dc.identifier.urihttps://hdl.handle.net/20.500.12395/29528
dc.identifier.volume10en_US
dc.identifier.wosWOS:000324136800005en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF COATINGS TECHNOLOGY AND RESEARCHen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectPolystyreneen_US
dc.subjectChemical modificationen_US
dc.subjectAcylationen_US
dc.subjectAdhesion studiesen_US
dc.subjectCorrosion resistanceen_US
dc.subjectFractionalizationen_US
dc.titleFractionation effects of polystyrene on acylation reaction and their adhesive and corrosive propertiesen_US
dc.typeArticleen_US

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