Shear flocculation of celestite with sodium oleate and tallow amine acetate: effects of cations

Yükleniyor...
Küçük Resim

Tarih

2004

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

ACADEMIC PRESS INC ELSEVIER SCIENCE

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

Sodium oleate and tallow amine acetate (TAA) were used as surfactants for the shear flocculation of celestite. The shear-flocculation power values obtained with sodium oleate were higher than those obtained with TAA in terms of the concentrations used in the shear-flocculation experiments. In addition, sodium oleate and TAA were more effective on the celestite suspension in the pH ranges of 7-11 and 6-10, respectively. For the shear-flocculation experiments with sodium oleate at pH 11, with preaddition of calcium or magnesium ions at 5 x 10(-5) M and lower concentrations into the suspension, the shear-flocculation of the celestite suspension was promoted by the coagulation process due to the calcium and magnesium cations added. However, the shear-flocculation power values decreased due to the interaction between surfactant and cations at concentration values higher than 5 x 10-5 M for magnesium ions and 10(-3) M for calcium ion. Particularly, magnesium ions significantly reduced the shear-flocculation power values by slime coating of Mg(OH)(2) precipitates. (C) 2004 Elsevier Inc. All rights reserved.

Açıklama

Anahtar Kelimeler

celestite, shear flocculation, surfactant, cation

Kaynak

JOURNAL OF COLLOID AND INTERFACE SCIENCE

WoS Q Değeri

Q2

Scopus Q Değeri

Q1

Cilt

273

Sayı

1

Künye