Excess molar volumes and viscosities of binary mixtures of epichlorohydrine and alcohols

Küçük Resim Yok

Tarih

2005

Yazarlar

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

INTERPERIODICA

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Excess molar volumes (V-E) and viscosities were evaluated for binary mixtures of epichlorohydrine and alcohols (ethyl alcohol, methyl alcohol, i-propyl alcohol, and t-butyl alcohol) at 298.15 to 306.15 K. Excess molar volumes V-E were computed from density, while the excess Gibbs free energy of activation G*(E) was calculated from viscosity deviation eta. The results were applied to the Redlich-Kister equation. It was observed that all mixtures showed negative and positive values of V-E, evidently due to increased physical and chemical interactions between the components.

Açıklama

Anahtar Kelimeler

Kaynak

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY

WoS Q Değeri

Q4

Scopus Q Değeri

Q4

Cilt

79

Sayı

7

Künye