Rapid and real-time detection of arginine enantiomers by QCM sensor having a Calix[4]arene receptor bearing asymmetric centers

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dc.contributor.authorTemel, Farabi
dc.contributor.authorErdemir, Serkan
dc.contributor.authorOzcelik, Egemen
dc.contributor.authorTabakci, Begum
dc.contributor.authorTabakci, Mustafa
dc.date.accessioned2020-03-26T20:19:12Z
dc.date.available2020-03-26T20:19:12Z
dc.date.issued2019
dc.departmentSelçuk Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümüen_US
dc.description.abstractThis paper describes the sensing studies of a chiral calix[4]arene receptor (5) having (R)-2-phenylglycinol moiety for arginine enantiomers (D-/L-arginine) by using Quartz Crystal Microbalance (QCM) technique. The initial experiments have revealed that the chiral calix[4]arene 5 coated QCM (CCC-QCM) sensor showed good sensing for arginine enantiomers, such that it has exhibited higher sensing towards D-arginine than that of L-arginine. It has been determined that the sensitivity, limit of detection values of CCC-QCM sensor for the D-/L-arginine solutions as 0.024/0.023 Hz/mu M and 0.38/1.29 mu M, respectively. On the other hand, the racemic mixture studies were optimized using the response surface methodology with central composite design. Consequently, it has been demonstrated that the QCM sensor modification with a calix[4]arene receptor bearing asymmetric centers provided rapid, real-time, sensitive and effective sensing of arginine enantiomers.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK-Grant)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [115Z249]; Research Foundation of the Selcuk UniversitySelcuk University [16401003]; Konya, Turkeyen_US
dc.description.sponsorshipWe thank the Scientific and Technological Research Council of Turkey (TUBITAK-Grant Number 115Z249) and the Research Foundation of the Selcuk University (SUBAP-Grant Number 16401003), Konya, Turkey and for financial support of this work produced from Farabi Temel's Ph.D. Thesis.en_US
dc.identifier.citationTemel, F., Erdemir, S., Ozcelik, E., Tabakci, B.,Tabakci, M. (2019). Rapid And Real-Time Detection Of Arginine Enantiomers By QCM Sensor Having A Calix [4] Arene Receptor Bearing Asymmetric Centers. Talanta, 204, 172-181.
dc.identifier.doi10.1016/j.talanta.2019.05.093en_US
dc.identifier.endpage181en_US
dc.identifier.issn0039-9140en_US
dc.identifier.issn1873-3573en_US
dc.identifier.pmid31357279en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage172en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.talanta.2019.05.093
dc.identifier.urihttps://hdl.handle.net/20.500.12395/38147
dc.identifier.volume204en_US
dc.identifier.wosWOS:000480664200019en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.institutionauthorTemel, Farabi
dc.institutionauthorErdemir, Serkan
dc.institutionauthorOzcelik, Egemen
dc.institutionauthorTabakci, Mustafa
dc.language.isoenen_US
dc.publisherELSEVIERen_US
dc.relation.ispartofTALANTAen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectArginineen_US
dc.subjectCalixareneen_US
dc.subjectSensingen_US
dc.subjectQuartz crystal microbalanceen_US
dc.subjectSensoren_US
dc.subjectAmino aciden_US
dc.titleRapid and real-time detection of arginine enantiomers by QCM sensor having a Calix[4]arene receptor bearing asymmetric centersen_US
dc.typeArticleen_US

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