Synthesis, molecular structure, spectroscopic studies and second-order nonlinear optical behaviour of N,N '-(2-hydroxy-propane-1,3-diyl)-bis (5-nitrosalicylaldiminato-N,O)-copper(II)
Küçük Resim Yok
Tarih
2007
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
PERGAMON-ELSEVIER SCIENCE LTD
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
N,N'-(2-Hydroxy-propane-1,3-diyl)-bis(5-nitrosalicylaldiminato-N,O)-copper(II) has been synthesized. The crystal structure has been determined by X-ray diffraction analysis, and linear optical characterization has been determined by UV-vis spectroscopy. It was found that the molecule under investigation has solvatochromic behaviour in the UV region, implying non-zero microscopic first hyperpolarizability. To reveal the microscopic nonlinear optical (NLO) properties, the static first hyperpolarizabilities (beta) and the electric dipole moments (mu) were evaluated by using the ab initio finite field (FF) method. According to the results of the FF calculations, the synthesized compound exhibits non-zero beta values, and it might have microscopic NLO behaviour. (c) 2006 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
copper(II) complex, crystal structure, second-order nonlinear optics, electric dipole moment, UV-vis spectroscopy
Kaynak
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
66
Sayı
04.05.2020
