Synthesis, molecular structure, spectroscopic studies and second-order nonlinear optical behaviour of N,N '-(2-hydroxy-propane-1,3-diyl)-bis (5-nitrosalicylaldiminato-N,O)-copper(II)

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dc.contributor.authorDonmez, Emine
dc.contributor.authorKara, Hulya
dc.contributor.authorKarakas, Asli
dc.contributor.authorUnver, Huseyin
dc.contributor.authorElmali, Ayhan
dc.date.accessioned2020-03-26T17:18:20Z
dc.date.available2020-03-26T17:18:20Z
dc.date.issued2007
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractN,N'-(2-Hydroxy-propane-1,3-diyl)-bis(5-nitrosalicylaldiminato-N,O)-copper(II) has been synthesized. The crystal structure has been determined by X-ray diffraction analysis, and linear optical characterization has been determined by UV-vis spectroscopy. It was found that the molecule under investigation has solvatochromic behaviour in the UV region, implying non-zero microscopic first hyperpolarizability. To reveal the microscopic nonlinear optical (NLO) properties, the static first hyperpolarizabilities (beta) and the electric dipole moments (mu) were evaluated by using the ab initio finite field (FF) method. According to the results of the FF calculations, the synthesized compound exhibits non-zero beta values, and it might have microscopic NLO behaviour. (c) 2006 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.saa.2006.05.027en_US
dc.identifier.endpage1146en_US
dc.identifier.issn1386-1425en_US
dc.identifier.issue04.05.2020en_US
dc.identifier.pmid16872883en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1141en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.saa.2006.05.027
dc.identifier.urihttps://hdl.handle.net/20.500.12395/21641
dc.identifier.volume66en_US
dc.identifier.wosWOS:000245480400055en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherPERGAMON-ELSEVIER SCIENCE LTDen_US
dc.relation.ispartofSPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectcopper(II) complexen_US
dc.subjectcrystal structureen_US
dc.subjectsecond-order nonlinear opticsen_US
dc.subjectelectric dipole momenten_US
dc.subjectUV-vis spectroscopyen_US
dc.titleSynthesis, molecular structure, spectroscopic studies and second-order nonlinear optical behaviour of N,N '-(2-hydroxy-propane-1,3-diyl)-bis (5-nitrosalicylaldiminato-N,O)-copper(II)en_US
dc.typeArticleen_US

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