Selective Chiral Recognition Of Alanine Enantiomers By Chiral Calix [4] Arene Coated Quartz Crystal Microbalance Sensors

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dc.contributor.authorTemel, Farabi
dc.contributor.authorErdemir, Serkan
dc.contributor.authorTabakçı, Begüm
dc.contributor.authorAkpınar, Merve
dc.contributor.authorTabakçı, Mustafa
dc.date.accessioned2020-03-26T20:19:16Z
dc.date.available2020-03-26T20:19:16Z
dc.date.issued2019
dc.departmentSelçuk Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümüen_US
dc.description.abstractWe describe the synthesis of new chiral calix[4]arene derivatives having (R)-1-phenylethylamine, (S)-1-phenylethylamine, (R)-2-phenylglycinol, and (S)-2-phenylglycinol moieties, and chiral recognition studies for enantiomers of some selected -amino acid derivatives such as alanine, phenylalanine, serine, and tryptophan using a quartz crystal microbalance (QCM). Initial experiments indicated that the highest selective chiral recognition factor was 1.42 for alanine enantiomers. The sensitivity, limit of detection, and time constant for l-alanine were calculated as 0.028 Hz/M, 60.9 M, and 36.2 s, respectively. The results indicated that real-time, sensitive, selective, and effective chiral recognition of alanine enantiomers was achieved with a QCM sensor coated with a chiral calix[4]arene derivative having (R)-2-phenylglycinol moieties.en_US
dc.description.sponsorshipTechnical Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [115Z249]; Research Foundation of Selcuk University (SUBAP grant), Konya, Turkey [16401003]en_US
dc.description.sponsorshipWe thank the Technical Research Council of Turkey (TUBITAK grant number 115Z249) and the Research Foundation of Selcuk University (SUBAP grant number 16401003), Konya, Turkey, and for financial support of this work produced from FT's Ph.D. thesis.en_US
dc.identifier.citationTemel, F., Erdemir, S., Tabakci, B., Akpinar, M., Tabakci, M. (2019). Selective Chiral Recognition Of Alanine Enantiomers By Chiral Calix [4] Arene Coated Quartz Crystal Microbalance Sensors. Analytical And Bioanalytical Chemistry, 411(12), 2675-2685.
dc.identifier.doi10.1007/s00216-019-01705-5en_US
dc.identifier.issn1618-2642en_US
dc.identifier.issn1618-2650en_US
dc.identifier.issue12en_US
dc.identifier.pmid30931505en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s00216-019-01705-5
dc.identifier.urihttps://hdl.handle.net/20.500.12395/38183
dc.identifier.volume411en_US
dc.identifier.wosWOS:000464948100021en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.institutionauthorTemel, Farabi
dc.institutionauthorAkpinar, Merve
dc.institutionauthorTabakci, Mustafa
dc.language.isoenen_US
dc.publisherSPRINGER HEIDELBERGen_US
dc.relation.ispartofANALYTICAL AND BIOANALYTICAL CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectAmino aciden_US
dc.subjectCalixareneen_US
dc.subjectAlanineen_US
dc.subjectChiral recognitionen_US
dc.subjectQuartz crystal microbalance sensoren_US
dc.titleSelective Chiral Recognition Of Alanine Enantiomers By Chiral Calix [4] Arene Coated Quartz Crystal Microbalance Sensorsen_US
dc.typeArticleen_US

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